She looks really cool. ^_^ Love the color combination all over the picture. The style is very interesting as well. The scepter, the crown and the cape suits Twilight a lot, even she looks kinda crazy with those on... XD
Which Chaotic? Chaotic Good, Chaotic Neutral, or Chaotic Evil? (Bit of Dungeons & Dragons in me couldn't resist the title on that.) "Twilight is ready to take over Equestria and nothing will stand in her way. Long live the Empress!" That clearly in either Chaotic Neutral or Chaotic Evil.